You can use the Port Config.VI and the Port Write.VI to perform the operation you want to do. There are DIO shipping examples in LV 6i which are designed to be used with the 8255 PPI boards, like yours. If you can find them in Search Examples-> I/O Interfaces -> Data Acquisition -> Digital Input and Output -> Immediate Digital Input and Output. You may have to modify them a little bit, but they are a good start point.