Hi Steve,
I am currently working on a project where I had to do what you are asking. The card I am using is a HS-6533 because I needed to be able to clock data at 375KHz. My application requires both transmitting and receiving a serial bit stream. In my app the transmitted words are 11 bits.
What you need to do is set your DIO card to write to 1 line. There are some examples under Hardware Input output/Traditional DAQ (LabVIEW Examples). They may not be much help (they were not for me).
Next format your data into a string of 1's and 0's which represents the correct data format for your application. This is then converted to a numeric array or you could skip the first part and just create the numeric data array. Next pass this numeric array to the DIO Write VI. There is more to it than this but I wanted to present the basic concept.
I can send you my custom solution if you are interested. You should be able to build your own by using mine as an example.
Pat
Pat