IMAQ configure trigger looks like it will do the job. As I'm running on LabVIEW 6.1 I wasn't aware of the second option.
Out of interest though, how would I go about the last suggestion you made? Would this just involve looking at the line state at all times and then jumpng out of a loop when the state has changed? Sorry, but my understanding of the use of RTSI is limited.
Thanks already for the advice.