You are correct! Some digitizers can acquire data faster than the PCI bus can transfer it, so currently the highest sampling rate you can aquire continuously with is around 30MS/s (using the 5112 and depending on your PC of course). We are working on our driver to get the number closer to the specifications of the PCI bus. Page 5-7 of the NI-Scope Software Users Manual will give you more information on continuous data acquisition with NI Digitizers.
Josh doesn't the PCI transfer speed depend on whther the card is operating as a Master or a Slave. In master modes the speeds should be much higher than 30MB/s.