Easy enough. Wire the same trigger you wired to PFI0 on the DAQ card to PFI0 or PFI1 on the scope card. Set this input up as the start trigger for the scope (Start Trigger (Acq. Arm)->Source property), and use the analog trigger normally.
There are also ways you can do this connecting wires from the DAQ card to the scope. See previous post and substitute start trigger for reference trigger.
So far as I know, there is no way to route the PFI0 from a PCI DAQ card to a PCI NI-SCOPE card without a physical wire, be it PFI to PFI or a RTSI cable. PXI makes this easy, since the RTSI lines are built into the backplane.
Good luck.