After re-reading your question, it seems that you may be asking if it possible to have BOTH a RS-232 port and a RS-422 port on the computer at the same time. It is possible if you install additional hardware for the RS-422 port. For example, NI-Serial RS-485 interfaces can give you 2-8 RS-422/485 serial ports in addition the whatever on-board RS-232 ports came with your computer.