If its for experimental use, you can do this.
Take the Tx signal from your computer and route that to all Rx inputs of the slave devices.
Do not tie together the outputs of the devices to your PC.
You may need to use a null-modem setup on the computer-side to resolve a possible flow-control issue (handshaking).
If the load is an issue (your computer is to weak to electrically drive all devices), you can drive your RS-232 signal using some electronics.