Hi Suren,
The LabVIEW Embedded Module for ARM Microcontrollers uses the "Keil uVision development toolchain to compile, download, and debug applications" as this article explains. (ARM Devices Supported by LabVIEW)
With this in mind, you should be able to use any microcontroller that supports the "RL-ARM Real-Time Library." The Keil Device Database lists the currently supported microcontrollers with this library. (RL-ARM Real-Time Library)
The Freescale MC9S12XEP100RMV microcontroller is not listed as being supported. Knowing this, you may not be able to use the LabVIEW Embedded Module for ARM, but you could use the LabVIEW Microprocessor SDK Module. The only difference is that the ARM Module has been built out of the SDK Module. The SDK Module is more "generic" and allows you to develop the supporting software for basically any 32-bit microcontroller.
I hope this helps,
Kevin S.
Applications Engineer
National Instruments
