In short:
If the code tries to initialize and use port 10 as a serial port it should work without any issues as long as the hardware indeed supports this.
Background:
By default VISA will associate ASRL 10 with parallel ports and you have to manually modify the visaconf.ini file to be able to use it as a serial port instead. This is very cumbersome and not very intuitive for the users (if a serial port is installed and grabs port 10 (the fact that it can and will do this is alone a reason not to have the current behaviour) they do not understand why it does not work).
Serial ports are still quite common compared to parallel ports, if VISA has to dedicate an alias to parallel ports like this it makes more sense to choose a number less likely to conflict with serial ports - like COM99 or higher..
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