Hi,
Coded as it is, you are writing a binary file wtih ASCII characters in it. I supposed the extra character (02 hex) is there for delimiting the structure of the dataype you are writing. If the array you were writing was an 2D array of floats for example, you wouldn't even be able to read the file in a "human manner"--> see the LabVIEW shipped examples on binary files for more info.
If what you want to do is writing a file wich can be displayed/edited in a text editor, use the write to spreadsheet files/string functions on which you can also find examples shipped with LabVIEW
Regards,
Cyril Bouton
Active LabVIEW Developper