The best suggestion I can offer is a DLL. However; I don't know how to call a DLL from the command line.
Other than that, and all kinds of different fancy tricks to try to make the front panel invisible, I can't offer anything, except for the following:
1) LabVIEW is not capable of creating command-line executables.
2) If you can run this as a normal executable, but just want to get rid of the front panel, then you can use VI server within your main VI to set the VI so that the front panel isn't displayed. I predict that the front panel will be displayed momentarily anyway, but this depends on your system as to whether or not you will be satisfied with the results.
3) Create a simple C/C++ program (even I could do this, and I don't know C that
well) that calls your executable as a DLL (you will obviously have to rebuild your VI, as DLLs are structured differently - a main VI is not required, but rather, one VI per function.) This can be built, and then run from the command line.
4) Please write to NI and suggest that this be an option for future versions of LabVIEW. I have seen too many uses for this kind of feature, and think it would be great to see LabVIEW be as versatile and powerful as C/C++.
Good luck