With the DAQ Assistant, when you get a list of 'Supported Physical Channels', look at the bottom of the window. It says "<Ctrl> or <Shift> click to select multiple channels. When you use the DAQmx Create Channel and have a physcial channel control/constant, click the little arrow on the right side of the control/constant, select browse and use the same <Ctrl> or <Shift> click technique. If you want to enter the channels manually, the format is Dev1/ai0:2 for consecutive or Dev1/ai0,Dev1ai3 non-consecutive channels.