Eric,
There were no subvis, but one express vi was used to generate a signal. I removed that; so, it should not be a problem now. You can build the exe and you'll see it works in the development and crashes as an exe.
Since it only crashes as an exe, LabVIEW does not ask to debug.
Here's the details from the windows crash report:
AppName: export crash.exe AppVer: 1.0.0.0 ModName: lvrt.dll
ModVer: 8.5.0.4002 Offset: 001bdacf
If I press the debug window, it reports an unhandled exception (see attached pic)