ilogix-
The easiest way to write to the serial port in LabVIEW is with the Port Out.vi. You can find the help info
here. You can find the address of the parallel port in the properties (located in Control Panel>>System>>Hardware Tab>>Device Manager) under the Resources tab. IT is the first number in the I/O range property (usually 0378).
This is a digital line and the parallel port is written as a byte so your labVIEW program will need to write a byte, delay and write another byte to get a "waveform".
Xaq