I am not sure about your question.
An Hex command is nothing but a string with chars that are not always alphanumerics (under $20). To write/display such a string in LV, just right click the string control, then select "Hex display". Another way of manipulating such strings is the "\ code display" option, where control chars appear as \i chars.
Hope this helps !
If you have other problems with serial port communication don't hesitate to ask.
Chilly Charly (aka CC)