Hi.
If the data with which you create your chart is "smooth", you could simply take the derivative of that data, and see where it changes sign, thus providing information of local peaks. You could then take a look at those points and see which are minima, which are maxima, and their values, to take the ones that interest you the most (i.e., the highest maxima).
LabVIEW has a Derivative x(t).vi to get the derivative of an array (containing the points you used to generate the chart), located in Functions > Analyze > Signal Processing > Time Domain.
If the data is not smooth, then you will have a lot of derivative sign changes, so you need to do something else, like look for all values of the array that are over 90% of the maximum value of the array, or something of the sort.
Is your data smooth?
Alejandro