Dear Andreas,
There is a useful KnowledgeBase article that helps with the configuration of your sound card for inputs other than the mic input.
Search for the following article: 2JRJQ6EU
In brief: the control over the recording source is at OS level rather than application level i.e. you can't directly select the line input from LabVIEW but need to use utilities provided with the OS or sound card. The article has more detailed advice on the matter.
Best wishes
Jeremy