Hello,
I heard back from R&D about this issue. They indicate that since Solaris uses loadable kernel modules and doesn't require users to recompile/relink the kernel, there may not be any way to change the system default window size. You could, however, write a LabVIEW CIN (or link to a shared library) which takes the LV TCP refnum, looks up the associated socket descriptor, and calls setsockopt on it to change the TCP Window size for the connection. Although it would be rather involved, this is the only way to change the size of which R&D is aware.
I hope this sheds some light on the situation for you. I wish you luck with your application. Have a pleasant weekend.
Sincerely,
Darren Nattinger
Applications Engineer
National Instruments