Yes this works with continous sampling mode. What you can do is first set the property "RelativeTo" to "current", then set the property "offset" to 0, then do an AI Unscaled Read then set the property node "offset" to the negative number of points you've read, then finally do an AI Scaled Read.
That way in a loop you'd acquire both unscaled and scaled data.
I've had another problem with the scaling of unscaled data though. With an SCXI 1141 I'm getting different values from scaled and unscaled data. I scaled my unscaled binary data with property "ScaleCoeff", but the scaled values are off by a few counts.
Hope this helps,
Dan