Hi Arun,
This should help you a little:
http://www.keil.com/mcb2300/mcb2300-schematics.pdf
The data sheet shows a Pin description in section 6.2. The SPI pins are of course muxed, but it looks like they are all reachable:
pin 86: MOSI
pin 87: MISO
pin 89: SCK
pin 90: SSEL
TO program in LabVIEW, you can use the SPI VIs that are included in the module.
-Jaidev
Senior Product Manager
National Instruments