Since you haven't attached the example, all I can do is explain how the LabVIEW shipping example (Write Table to XL.vi) works and how it can be modified. The shipping example has an Open Excel, Open Book, Open Sheet and, some functions for labeling rows and columns, and then a for loop for adding data. Copy the preliminary stuff for creating and opening and put it in your VI at the very beginning so that it's called once. Then, where you want to repeatedly write, just copy the Add Data function (it's called Set Cell Value.vi) Make sure that you pass it the Excel reference and keep incrementing the row value by the number of rows you write each time. Your example probably does something similar. You just have to find the part that does the actual writing
and separate it out from the initial and closing functions.