Hi,
This is the general method I would suggest:
You could use an Event Structure to read a mouse click or keyboard button press, which in turn, when the event is triggered, would then set a digital output (for example) on your 6251 high, which would be wired into the trigger input for the 6251. This would then start the triggered acquisition. If you have any other questions regarding this I'll be happy to answer them.
Regards,
Dan - NIUK