If you go to NI-Serial Help and search for "pin", the pinout for 485/422 can be found. The NI-Serial help is located under Start»All Programs»National Instruments»NI-Serial»NI-Serial Help. Go to the search tab and search for "pin". Then click on DB-9 Connector page. The pinout for a 485 signal will be the same as 422.
Also, the Serial Quick Reference Guide shows this information. Below is a link.