As Troy mentioned, it would help to know which version of LabVIEW you are using. In LabVIEW 8.2, for example, you can create an installer and use the Source Files category to place various files needed for your application in different locations.
The key point is that you can include support files when building an EXE, which places them in the data folder, or you can explicitly choose where they will be installed by including your support files one-by-one in an installer. In case you simply wish to create an EXE and manually copy over the generated files, you would have to include all support files when building the EXE.
I hope this helps!
Casey Weltzin
Applications Engineer
National Instruments