Also remember that what you are writing is not a microsoft excel file at all and giving it an *.xls extension does not change that fact. Extension *.xls is reserved for the proprietary microsoft format and should not really be used for plain ASCII files as you do here. (Open your file and a real excel file both in notepad, you'll see the difference ;))
Fortunately, excel is forgiving enough to automatically try its best to read any oddly formatted file having an .xls extension and tries to make sense of it. Don't count on the results to be always as expected.
I would recommend to give a better extension. For example you could separate your fields with commas and write it as *.csv file (that's what it now really is!). By default, *.csv files also open with excel, except in this case excel knows what it is supposed to be.
🙂(You can write genuine xls files in LabVIEW, but it is a bit more complicated. Search for excel in your example browser for some tips.)