Hello Mike,
Thank you for contacting National Instruments.
Another way to do this would be to use the Get Date/Time in Seconds function in LabVIEW to get the time at the beginning of the capacitor charge curve. Then as you read in voltages, compare them to the 63% of total charge. As soon as 63% charge is reached, use another Get Date/Time in Seconds, and from that value subtract the initial time. The result will be the elapsed time in seconds.
I hope this helps,
Sean C.
Applications Engineer
National Instruments