Starting in Windows NT, Microsoft came up with an optimization what was called application boosting. With application boosting, the operating system allocates resources to the foremost windows application to increase its performance. For example, you have Program A and Program B running at the same time. You click on Program A, bringing it to the front. With application boosting, Windows will allocate more resources to Program A than to Program B. In your case, opening an IE window would make it the foremost Window and take resources away from LabVIEW. Checking background services turns off application boosting.
In LabVIEW, try going to Tools»Options»Performance and Disk and check "Deallocate Memory as soon as Possible".
Also, I assume yo
u have a main loop in your code, put a small wait in the loop. 10 ms will do. This will allow windows to take care of background operations.