You did not say what word size you want, but you could e.g. take the subsctring of the first 6 characters and typecast it as an aray of 3 U16 elements.
Simply use typecast and wire an empty array diagram constant of U16 to the type input. It is possible that your binary string is little, endian. In this case you need to reverse the byte order. On newer version of LabVIEW, you can also use unflatten from string and specify the byte order directly (LabVIEW is always big-endian.)