The user manual is the best place to determine the specifications of your board. The
datasheet for the PCI-6014 says the maximum sampling rate is 200,000 samples / second. Try searching the shipping examples for analog input examples. I suggest trying "Cont Acq&Graph (buffered).vi" to start.
Are you trying to acquire a digital input or analog input? If you are sampling a time varying analog signal, you should be connected to an analog input channel on your card.
Tim