National Instruments has a number of simultaneous sampling hardware. Unfortunately, this is the ONLY way to get absolutely simultaneous sampling of data. However, having used one of them myself, I am highly impressed with their boards. Very easy to use, of course, but also, very, very clean signals.
I used a four channel model, the NI 6110, about a couple of years ago. I strongly recommend using a BNC 2100 series break-out box with it.