phod,
This is the LabVIEW Real-Time forum, so I suggest that in the future that you post this type of question to the Multifunction DAQ forum.
For the simplest solution you will have to connect your button to a digital line of your board, consult the sc-2345 user manual for a diagram of where these lines are exposed. You will have to connect your start button in series with a line that is high, such as your 5V pin or another digital line. Then connect this to a digital line that will be your start trigger.
Your program can poll the digital line that is connected to your button in a while loop and when it goes high, it lets the rest of the program execute. For the programming, I suggest you take a look at the shipping examples that come with LabVIEW. If yo
u have LabVIEW 7.0 go to Help>>Find Examples. Open Hardware Input Output>>Traditional DAQ>>Digital Input and Output>>E Series for some examples of digital I/O programming with E-series boards.
Hope that gets you started.
Gerardo