In any case, read/write to/from spreadsheet file does not work with native excel files. How to tell the difference? An empty excel file is already ~14kb in size, so if your files are smaller they are most likely not excel files.
Open some of your files using notepad. A real excel file will have lots of strange characters and you should not easily see the actual table data. A fake excel file will nicely show the table data, even in notepad.
I think writing your data directly into a proprietary microsoft format is overrated unless you need some of the fancy formatting (Different fonts, sizes, merged cells, etc.). Excel can import vitually any reasonable spreadsheet-like text written by LabVIEW. I sometimes write spreadsheet data as comma-
delimited ASCII table and name the file "*.csv". csv files also open in excel and there is no confusion about the format.