If the analog side can be considered master, maybe you can try using Digital Trigger Config.vi (in the Advanced Digital I/O palette) in order to start digital output on some I/O connector input, and connect this input with ScartScan output (or other acquisition timing output you want) on the connector.
On the other side, if you must start acquiring when digital I/O starts, maybe you can play a while with AI Trigger Config.v in order to syncronize the two processes with the digital side mastering the other.
Sorry for generic response: I hadn't performed such task till now, but I'm now in trouble with syncronizing AI and AO and found a NI example that extensively use triggering instruments in order to syncronize the two processes, and I think this could apply to
your situation.
Roberto