Hi labview1958,
You're probably way past this now. but if not...
It might be good to understand the difference between the DMM and the values seen on your VI's FP. I'd double-check that wiring and AI signal-reference settings (differential, RSE, NRSE) agree, and certainly look at the signal with a real (not virtual) oscilloscope - if one's available.
I take it you were reading single voltage values(?) If so, look to the LabVIEW Examples for "multi-point" (AKA "waveform") acquisitions. Dennis Knutson's directions will get you home.
Cheers.
When they give imbeciles handicap-parking, I won't have so far to walk!