In your Main.vi, you have the Set Cell Value.vi inside of a couple nested for loops. You've gotten this from the shipping example and it starts writing at row 2, column one which gets translated to cell A2. You can use Set Cell Value inside of a loop and initialize the starting row/column to anything you want and then write to one cell at a time. The alternative is to just use the worksheet.range method, specifying cell 1 and cell 2, and write a whole range of data at once using range.value property. I haven't had to do this in quite a while and don't have an example handy but the Excel VBA help should have the information you need. There are also a lot of other Excel examples
here that you might want to look at.