Hello Chris,
Yes it is possible to have more than five (5) loops when using the LabWindows/CVI PID Control Toolkit. If you open the pid.c source code, you will find an enumeration near the top "#define NLOOPS 5". Change the number after NLOOPS to the maximum number of loops that you desire to control. This is explained further on page 1-9 of the "LabWindows/CVI PID Control Toolkit Reference Manual", available online at "http://www.ni.com/manuals".
Jeremiah Cox
Applications Engineer
National Instruments
http://www.ni.com/ask