According to the on-line documentation, the formulas used are:
CVI:
sDEV = Sqrt{Sum(for i=0 to n-1) [x(i)-mean]**2/n]}
(Right click in the function panel window, NON on the parameters of the function, OR right click on any parameter and then select Function help... in the help window)
EXCEL:
sDev = Sqrt{[n*Sum(x**2) - [Sum(x)]**2] / [n*(n-1)]}
As you see the two algorithm are very different.
I'm sorry I can't help you with more detail: I'm not a statistic expert, so I can't discuss if they are equivalent (seems they're not) or which of them is the right one (if a 'right' one exists!).
Hope it helps
Roberto