I never tried such an application in CVI, but having used it in LabVIEW I can suggest you a workoround based on LV applications.
You could try with this steps:
1. Configure AI acquisition as desired
2. Configure WFM generation as desired
3. Set output start trigger as AI start trigger using Select_Signal function:
Select_Signal (1, ND_OUT_START_TRIGGER, ND_IN_START_TRIGGER, ND_DONT_CARE);
4. Start AI acquisition: this should start WFM generation as well
For an example on how to use Select_Signal look at WFMsingleBufExtTrig_Eseries.prj example shipped with CVI.
Roberto