Nathan,
You can have access to the serial interface through imgSessionSerialWrite and imgSessionSerialRead in IMAQ.dll. These low-level functions are not documented because most of the serial communications should be taken care of by the camera file. This function is still available for use when serial commands needed are not implemented.
For LabVIEW, you can find these low-level VIs in \vi.lib\vision\driver\imaqll.llb
Hope this helps.
Ken
Applications Engineering
National Instruments