hey Chris -
Thanks for the quick reply! That was a great suggestion - when I test the center/shield of DAC0 with a DMM (DC mode, right?), I don't see the offset. I've also since discovered that I can also change the size of the offset by changing which receptacle the oscilloscope is plugged into. So it's probably a ground loop between the PC and my various measuring devices.
Unfortunately, that's not my biggest problem anymore, since I seem to have altered my labview installation while trying to get the most up-to-date diagnostic tools, and now my application doesn't run (new thread here: http://forums.ni.com/ni/board/message?board.id=250&thread.id=35361). Your expertise is most welcome on this one as well!
Gene