Ian,
Don't worry this can take some time to fully understand all your options. If you are only scanning one channel ie using DAQ calls the trigger line will be the same as the data line. (This is how the example is setup, they just picked Channel 1, but could be zero as well). If you want to scan one channel and trigger from another, and are NOT using diff mode, then you can wire your analog trigger directly to PFI0, which is the line used for triggering the acquisition. If you want to scan more then one channel (using the SCAN functions) the trigger signal will be the first channel in your scan list. So if you are using differential mode and Channel 1(pos wire -> AI1 and neg -> AI9). Then your other data line must be 2-7.
The simplest solution
would be to not use diff mode, wire the trigger to PFI0 and the data line to any other AI channel. Differential mode is preferable however and may be the only solution depending on your source. In this case use the SCAN functions and setup your scan list for 0,1. Your trigger will be connected to differential channel 0, and your data will be connected to Channel 1.
Hopefully this made things a little clearer. If not, well see if there are some other specific points I can clear up.
Kevin R