To preface my answer, here is some information that is located on our website ( FAQ for LabVIEW Student Edition). http://www.ni.com/labviewse/labviewse_faq.htm.
Can I get technical support for LabVIEW Student Edition?
There will NOT be any direct (voice or e-mail) technical support for the LabVIEW Student Edition. Students are asked to consult their instructors about their problems.
Note: The LabVIEW Student Edition is available to students, faculty, and staff for personal educational use only. It is not intended for research or institutional use. For more information about institutional or research licensing, please follow this link for information on our Academic Site Licensing.
That being said, the reason the PCI-6013 won't work with the LabVIEW
6i Student Edition (SE) is that only an old and "modified" version of the NI-DAQ driver works with the SE. That board was not yet released at the time of that driver release, thus not supported in the SE. Apparently, that board will work in version 7 of the LabVIEW SE, provided that the appropriate drivers are installed. This can be found through the following KnowledgeBase (KB).
KB 2ZK6EHQJ
Drivers for LabVIEW 7.0 Express Student Edition
http://digital.ni.com/public.nsf/websearch/AA99FA8704D5E22686256D6A004464ED?OpenDocument
Keep in mind that you can program a DAQ board in other languages than LabVIEW such as C++, C, Visual Basic and .NET languages in you have any of these available to you.