It depends on your card. As far as I know, M-Series cards have only a single ADC, and therefore can only measure one channel at a time. Multi-channel measurements are thus time-interleaved. However, the time delay is quite small, ca. 5-50 microseconds, depending on your sampling rate. Slower sampling rates mean longer interleaving delays, but also better accuracy and much better channel separation.
I believe if you want true simultaneous sampling, you need a card with multiple ADCs, such as the S-Series.