Unfortunately, you will be unable to sample at two different rates at the same time. Your board consists of one multiplexer (MUX) and one analog to digital converter (ADC). This hardware only allows for one sample rate to be configured at a given time. You may scan at 330 samples/second on channel 0-3, stop, end the analog input task, and then proceed to configure a new analog input task where you sample at 100 samples/second from channels 4-5.
Regards,
Justin Britten
Applications Engineer
National Instruments