If you examine the User Manual for your 6023 board, or refer to the KnowledgeBase article linked below, you will find that your board has only 1 DMA channel. Each buffered operation requires the use of one DMA channel. Therefore, with your hardware, you are only able to program one buffered operation. The other operations must use interrupts to perform the data transfer.
How Many DMA Channels Does My E Series Data Acquisition (DAQ) Device Have?
http://digital.ni.com/public.nsf/websearch/E00C0F790CA2CDA686256BF000614DE1?OpenDocument
Also in this KnowledgeBase you will find that we have multiple boards which have up to 3 DMA channels.
Regards,
Justin Britten
Applications Engineer
National Instruments