You can synchronize multiple boards via the PXI-Backplane of the PXI-Chassis. You could for example route the Sample-Clock of the 6220 to all the other cards, so that they all use the same sample clock.
There is an example installed with the DAQmx driver (7.3) that synchronizes multiple boards. You can find it in the National Instruments-folder under the following path:
National Instruments\NI-DAQ\Examples\DAQmx ANSI C\Synchronization\Multi-Device