Hello Kristrio,
I went and went through these steps on a Windows 2000 machine with NI-Serial 1.7, and had no trouble. You can try to uninstall and re-install the hardware to make sure it gets associated properly with the driver. What version of NI-Serial are you using? I presume from your comments that you are unable to change the port assignment in MAX successfully? Did you upgrade your serial driver or install the driver after you upgraded CVI? You may have trouble communicating with your card if you did not install the driver after the other software. Also, it is a good idea to uninstall the old version before installing the new driver.
I hope this helps.
Regards,
Angela