Hi,
Yes, you can use the CI20 module to read in voltages. Connecting a voltage source in parallel with R3 will result in the same potential drop to appear across the R3 resistor (see diagram attached).
Make sure that you DO NOT configure the CI20 in the Measurement and Automation Explorer, so you can read the raw voltage. Also DO NOT supply more voltage than 5V, or you might damage the module.
Hope this helps,
Lesley Y.