Jack,
What do you have your Accelerometer connected to? The way most accelerometers work is that they are powered from a constant current source, i.e. 4mA. Then, they will generate a voltage based on movement which can be read by your measuring device. So, the constant current source is generally provide by the measuring device, or some signal conditioning that is attached to the measuring device, and the voltage generated by the accelerometer is read back into the device. The products that NI sells which provide this signal conditioning for accelerometers are our DSA boards - NI-44xx, SCXI-153x, SCC-ACC01, etc... If you have any of these, then you just need to create an Accelerometer task either in MAX or using the DAQ assistant in LabVIEW.
Take a look at the DAQ Quick Start Guide, which will hopefully answer many of your questions: http://www.ni.com/pdf/manuals/373235f.pdf
-Logan