I will expand on where Henrik was trying to lead you with his questions...
The main limiting factor on being able to sense a small change in the RTD (i.e. resolution) is going to be noise. Assuming that the RTD's noise is negligible, then the main source of noise in the measurements is the SCXI-1102. The averaged noise specification of the SCXI-1102 is 5uV, which means that any voltage change from the RTD smaller than 5uV will be lost in the noise.
If you use a very stable 100uA current source (the SCXI-1581 is the most common solution for RTD current excitation) then at 0degC a voltage change of 5uV on a 100 ohm RTD is equivalent to about a 0.13degC change in the RTD measurement. So, 0.13degC is the smallest temperature change that you will be able to sense at 0degC from your RTD - assuming that there is no noise from the lead wires of the RTD.
Let's say that you were able to average your data long enough that you could get the noise down to 1uV - this is still only 0.025degC of resolution. If you average your data for that long, I am willing to bet that the actual temperature has probably already changed by much more than 0.025degC.
The NI-4070 is probably the only solution from NI that will be able to give you a resolution of close to 0.01degC for an RTD.
Logan K
National Instruments R&D